AS Monaco FC 
1 vs 1 
PSV
1 vs 1 
PSVRecap
Speelronde 5
Toeschouwers: 17.000.
Scheidsrechter: Zeljko Siric (Kroatië).
Scoreverloop:
1-0 Fernando Morientes 34. (assist Julien Rodriguez)
1-1 Jan Vennegoor of Hesselink 84. (assist Arjen Robben)
AS Monaco FC: Akis Zikos (83)
AS Monaco FC: Ludovic Giuly (88)
PSV
| 23 | Ronald Waterreus Keeper | |
| 30 | Kasper Bøgelund 20 Verdediger |  (72) (39) |
| 4 | Ernest Faber Verdediger | |
| 5 | Wilfred Bouma Verdediger | |
| 3 | Young-Pyo Lee 25 Verdediger | (78) |
| 7 | Ji-Sung Park Middenvelder | |
| 14 | Johann Vogel Middenvelder | |
| 15 | Johann Vonlanthen 8 Aanvaller | (64) |
| 16 | Theo Lucius Middenvelder | (49) |
| 11 | Arjen Robben Aanvaller | (33) |
| 9 | Mateja Kezman Aanvaller | (88) |
| 8 | Jan Vennegoor of Hesselink 15 Aanvaller |  (64) (84) |
| 20 | Jürgen Colin 30 Verdediger | (72) |
| 25 | John de Jong 3 Middenvelder | (78) |
| 1 | Rob van Dijk Keeper | |
| 13 | Remco van der Schaaf Middenvelder | |
| 32 | Edson Rolando Silva Sousa Aanvaller | |
| 38 | Daniel Guijo-Velasco Middenvelder | |
| 3 3 1 3 1 | ||
Coach: Guus Hiddink
Gewisseld
Ingevallen
Goals
Penalty
Penalty Gemist
Yellow Cards
Yellow/Red Card
Red Cards
| 0 | 3 |
| 0 | 3 |
| 0 | 1 |
| 0 | 0 |
| 0 | 0 |
| 0 | 3 |
| 0 | 1 |
| 0 | 0 |